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SDS Product Code.

COA Batch No.

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Safety & Regulatory

GHS Pictogram (According to Globally Harmonized System of Classification and Labeling of Chemicals)
 
Hazard Symbols Hazard Precaution


Flammable substances. Self-reactive substances pyrophoric and self-heating substances.

Keep away from all sources of ignition. No smoking, keep container tightly.
           

 
Oxidizing substances. Organic peroxides. Oxidizing substances can cause fire in contact with combustible material or promote fire once started and impede fire fighting. Do not breath vapour
         

 
Skin corrosive. Eyes corrosive. Corrosive to metals. Causes burns. Contact with these substances causes destruction of living tissue as well as equipment. Do not inhale vapor. Never add water to this product.
           

 
Sensitization (Respiratory) Mutagenicity.
Carcinogenicity. Reproductive toxicity.
Target organ toxicity.
A substance which if inhaled, ingested or allowed to penetrate the skin may involve limited health risks. Possible risk of irreversible effects by immediate, prolonged or repeated exposure to these substances.
       

 
Acute toxicity. All contact with the human body must be avoided as it may cause severe or lethal damage to health. A substance which if inhaled, ingested or allowed to penetrate the skin may cause serious or chronic health damage and even death. Possible risk of irreversible damage by immediate, prolonged or repeated exposure.
             

 
Skin irritant. Eyes irritant. Sensitization (dermal). A substance which may have an irritating effect on skin, eyes and respiratory organs, possibility of sensitization by skin contact.
         

 
Environmental toxicity. Toxic for aquatic organisms. May cause long term adverse effects in the aquatic environment. Do not allow to enter waters, waste water or soil.
 

 
Explosives substances or articles.
Self-reactive substances.
A substance which either may explode under the effect of flame or which is more sensitive to shocks or friction than disturbance.
           

 
  Associated with compressed gase include oxygen displacemnt, fires, explosions, and toxic gas exposures as well as the physical hazards associated with high pressure system.  
   

 

GHS Statements
  • Hazard statement codes for physical hazards
    H200 : Unstable explosive
    H201 : Explosive; mass explosion hazard
    H202 : Explosive; severe projection hazard
    H203 : Explosive; fire, blast or projection hazard
    H204 : Fire or projection hazard
    H205 : May mass explode in fire
    H206 : Fire , blastor projection hazard; increased risk of explosion if desensitizing agent is reduced
    H207 : Fire or projection hazard; increased risk of explosion if desensitizing agent is reduced
    H208 : Fire hazard; increased risk of explosion if desensitizing agent is reduced
    H220: Extremely flammable gas
    H221: Flammable gas
    H222: Extremely flammable aerosol
    H223: Flammable aerosol
    H224: Extremely flammable liquid and vapour
    H225: Highly flammable liquid and vapour
    H226: Flammable liquid and vapour
    H227: Combustible liquid
    H228: Flammable solid
    H229: Pressurized container: may burst if heated
    H230: May react explosively even in the absence of air
    H231: May react explosively even in the absence of air at elevated pressure and/or temperature
    H232: May ignite spontaneously if exposed to air
    H240: Heating may cause an explosion
    H241: Heating may cause a fire or explosion
    H242: Heating may cause a fire
    H250: Catches fire spontaneously if exposed to air
    H251: Self-heating; may catch fire
    H252: Self-heating in large quantities; may catch fire
    H260: In contact with water releases flammable gases which may ignite spontaneously
    H261: In contact with water releases flammable gas
    H270: May cause or intensify fire; oxidizer
    H271: May cause fire or explosion; strong oxidizer
    H272: May intensify fire; oxidizer
    H280: Contains gas under pressure; may explode if heated
    H281: Contains refrigerated gas; may cause cryogenic burns or injury
    H290: May be corrosive to metals

    Hazard statement codes for health  hazards
    H300: Fatal if swallowed
    H301: Toxic if swallowed
    H302: Harmful if swallowed
    H303: May be harmful if swallowed
    H304: May be fatal if swallowed and enters airways
    H305: May be harmful if swallowed and enters airways
    H310: Fatal in contact with skin
    H311: Toxic in contact with skin
    H312: Harmful in contact with skin
    H313: May be harmful in contact with skin
    H314: Causes severe skin burns and eye damage
    H315: Causes skin irritation
    H316: Causes mild skin irritation
    H317: May cause an allergic skin reaction
    H318: Causes serious eye damage
    H319: Causes serious eye irritation
    H320: Causes eye irritation
    H330: Fatal if inhaled
    H331: Toxic if inhaled
    H332: Harmful if inhaled
    H333: May be harmful if inhaled
    H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled
    H335: May cause respiratory irritation
    H336: May cause drowsiness or dizziness
    H340: May cause genetic defects  (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
    H341: Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
    H350: May cause cancer  (state route of exposure if it is conclusively proven that no other routes of
    exposure cause the hazard)
    H351: Suspected of causing cancer (state route of exposure if it is conclusively proven that no other routes of
    exposure cause the hazard)
    H360: May damage fertility or the unborn child (state specific effect if known) (state route of exposure if it is
    conclusively proven that no other routes of exposure cause the hazard)
    H361: Suspected of damaging fertility or the unborn child (state specific effect if known) (state route of
    exposure if it is conclusively proven that no other routes of exposure cause the hazard)
    H362: May cause harm to breast-fed children
    H370: Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is
    conclusively proven that no other routes of exposure cause the hazard)
    H371: May cause damage to organs (or state all organs affected, if known) 
    (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
    H372: Causes damage to organs (state all organs effected,if known) through prolonged or repeated exposure
    (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
    H373:  May cause damage to organs (state all organs effected,if known)  through prolonged or repeated exposure   
    (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
    H300+H310: Fatal if swallowed or in contact with skin
    H300+H330: Fatal if swallowed or if inhaled
    H310+H330: Fatal in contact with skin or if inhaled
    H300+H310+H330: Fatal if swallowed, in contact with skin or if inhaled
    H310+H311: Toxic if swallowed or in contact with skin
    H301+H331: Toxic if swallowed or if inhaled
    H311+H331: Toxic in contact with skin or if inhaled
    H301+H311+H331: Toxic if swallowed, in contact with skin or if inhaled
    H302+H312: Harmful if swallowed or in contact with skin
    H302+H332: Harmful if swallowed or if inhaled
    H312+H332: Harmful in contact with skin or if inhaled
    H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled
    H303+H313: May be harmful if swallowed or in contact with skin
    H303+H333: May be harmful if swallowed or if inhaled
    H313+H333: May be harmful in contact with skin or if inhaled
    H303+H313+H333: May be harmful if swallowed, in contact with skin or if inhaled
    H315+H320: Causes skin and eye irritation

    Hazard statement codes or environmental hazards
    H400: Very toxic to aquatic life
    H401: Toxic to aquatic life
    H402: Harmful to aquatic life
    H410: Very toxic to aquatic life with long lasting effects
    H411: Toxic to aquatic life with long lasting effects
    H412: Harmful to aquatic life with long lasting effects
    H413: May cause long lasting harmful effects to aquatic life
    H420: Harms public health and the environment by destroying ozone in the upper atmosphere

    Codification of general precautionary statements
    P101: If medical advice is needed, have product container or label at hand
    P102: Keep out of reach of children
    P103: Read label before use

    Codification of prevention precautionary statements
    P201: Obtain special instructions before use
    P202: Do not handle until all safety precautions have been read and understood
    P210 Keep away from heat,hot surfaces,sparks, open flames and other ignition sources. No smoking.
    P211: Do not spray on an open flame or other ignition source
    P212: Avoid heating under confinement or reduction of the desensitized agent
    P220: Keep away from clothing and other combustible materials
    P222: Do not allow contact with air
    P223: Do not allow contact with water
    P230: Keep wetted with Keep wetted with for substances and mixtures which are wetted, diluted, dissolved or suspended 
    with a plegmatizer in order to suppress their explosive properties. Manufacturer/supplier or the competent authority to specify appropriate material.
    P231: Handle and store contents under inert gas. Manufacturer/supplier or the competent authority to specify appropriate 
    liquid or gas if I”nert gas” is not appropriate.
    P232: Protect from moisture
    P233: Keep container tightly closed
    P234: Keep only in original packaging
    P235: Keep cool
    P240: Ground and bond container and receiving equipment
    P241: Use explosion-proof
    P242: Use non-sparking tools
    P243: Take action to prevent static discharges
    P244: Keep valves and fittings free from oil and grease
    P250: Do not subject to grinding/shock/friction is the explosive if mechanically sensitive. Manufacturer/supplier or the competent authority 
    to specify applicable rough handing.
    P251: Do not pierce or burn, even after use
    P260: Do not breathe dust/fume/gas/mist/vapours/spray
    P261: Avoid breathing dust/fume/gas/mist/vapours/spray
    P262: Do not get in eyes, on skin, or on clothing
    P263: Avoid contact during pregnancy and while nursing
    P264: Wash … thoroughly after handling
    P270: Do not eat, drink or smoke when using this product
    P271: Use only outdoors or in a well-ventilated area
    P272: Contaminated work clothing should not be allowed out of the workplace
    P273: Avoid release to the environment
    P280: Wear protective gloves/protective clothing/eye protection/face protection
    P282: Wear cold insulating gloves and either face shield or eye protection
    P283: Wear fire resistant or flame retardant clothing
    P284: [In case of inadequate ventilation] wear respiratory protection
    P231+P232: Handle and store contents under inert gas/… Protect from moisture
    Codification of response precautionary statements
    P310: Immediately call a POISON CENTER/doctor. Manufacturer/supplier or the competent authority to specify the appropriate 
    source of emergency medical advice.
    P311: Call a POISON CENTER/doctor. Manufacturer/supplier or the competent authority to specify the appropriate source 
    of emergency medical advice.
    P312: Call a POISON CENTER/doctor/... / if you feel unwell
    P313: Get medical advice/attention
    P314: Get Medical advice/attention if you feel unwell
    P315: Get immediate medical advice/attention
    P320: Specific treatment is urgent (see … on this label)
    P321: Specific treatment (see … on this label)
    P330: Rinse mouth
    P331: Do NOT induce vomiting
    P334: Immerse in cool water[or wrap in wet bandages]
    P335: Brush off loose particles from skin
    P336: Thaw frosted parts with lukewarm water. Do not rub affected areas
    P338: Remove contact lenses, if present and easy to do. continue rinsing
    P340: Remove person to fresh air and keep comfortable for breathing
    P342: If experiencing respiratory symptoms:
    P351: Rinse cautiously with water for several minutes
    P352: Wash with plenty of water. Manufacturer/supplier or the competent authority may specify a cleansing agent if 
    appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.
    P353: Rinse skin with water [or shower]
    P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
    P361: Take off immediately all contaminated clothing
    P362: Take off contaminated clothing
    P363: Wash contaminated clothing before reuse
    P364: And wash it before reuse
    P372: Explosion risk
    P373: DO NOT fight fire when fire reaches explosives
    P375: Fight fire remotely due to the risk of explosion
    P376: Stop leak if safe to do so
    P377: Leaking gas fire : Do not extinguish, unless leak can be stopped safely
    P378: Use … to extinguish
    P380: Evacuate area
    P381: In case of leakage, eliminate all ignition sources
    P390: Absorb spillage to prevent material - damage
    P391: Collect spillage
    P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/...
    P301+P312: IF SWALLOWED: Call a POISON CENTER / doctor/.../if you feel unwell
    P302+P334: IF ON SKIN: Immerse in cool water[or wrap in wet bandages]
    P302+P352: IF ON SKIN: Wash with plenty of water. Manufacturer/supplier or the competent authority may specify a cleansing 
    agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.
    P304+P312: IF INHALED: Call a POISON CENTER /doctor/.../if you feel unwell
    P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing
    P306+P360: IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
    P308+P311: IF exposed or concerned: Call a POSION CENTER/doctor. Manufacturer/supplier or the content competent authority 
    to specify the appropriate source of emergency medical advice.
    P308+P313: IF exposed or concerned: Get medical advice/attention
    P332+P313: If skin irritation occurs: Get medical advice/attention
    P333+P313: If skin irritation or a rash occurs: Get medical advice/attention
    P336+P315: Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention
    P337+P313: If eye irritation persists: Get medical advice/attention
    P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER /doctor. Manufacturer/supplier or the content competent 
    authority to specify the appropriate source of emergency medical advice.
    P361+P364: Take off immediately all contaminated clothing and wash it before reuse
    P362+P364: Take off contaminated clothing and wash it before reuse
    P370+P376: In case of fire: Stop leak if safe to do so
    P370+P378: In case of fire: Use … for extinguish
    P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
    P302+P335+P334: IF ON SKIN: Brush if loose particles from skin. Immerse in cool water [or wrap in wet bandages]
    P303+P361+P353: IF ON SKIN (or hair) : Take off immediately all contaminated clothing. Rinse skin with water [or shower]
    P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
    P370+P380+P375: In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion
    P371+P380+P375: In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion
    P370+P372+P380+P373    : In case of fire : Explosion risk Evacuate area. DO NOT fight fire when fire reaches explosives.
    P370+P380+P375 [+P378] : In case of fire : Evacuate area. Fight fire remotely due to the risk of explosion.
    [Use…to extinguish]

    Codification of storage precautionary statement
    P401: Store in accordance with Manufacturer/supplier or the competent authority to specify local/regional/national/international regulations as applicable
    P402: Store in a dry place
    P403: Store in a well-ventilated place
    P404: Store in a closed container
    P405: Store locked up
    P406: Store in a corrosive resistant/… container with a resistant inner liner
    P407: Maintain air gap between stacks or pallets
    P410: Protect from sunlight
    P411: Store at temperatures not exceeding … ºC/… ºF
    P412: Do not expose to temperatures exceeding 50ºC/122ºF
    P413: Store bulk masses greater than …kg/…Ibs at temperatures not exceeding …ºC/… ºF
    P420: Store separately
    P402+P404: Store in a dry place. Store in a closed container
    P403+P233: Store in a well-ventilated place. Keep container tightly closed
    P403+P235: Store in a well-ventilated place. Keep cool
    P410+P403: Protect from sunlight. Store in a well-ventilated place
    P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF
    Codification of disposal precautionary statements
    P501 : Dispose of contents/container to in accordance with local/regional/nationnal/international regulation (to be specified). 
    Manufacture/suppiler or the competent authority to specify whether disposal requirements apply to contents, comtaineroe both.
    P501(cont’d) : Dispose of contents/container to in accordance with local/regional/national/international regulation (to be specified). 
    Manufacturer/supplier or the competent authority to specify whether disposal requorement apply to contents, container or both.
    P502 : Refer to manufacturer or supplier for information on recovery or recycling
    European European Union Supplemental Hazard Information (EUH-Statements)
    Physical properties
    EUH001: Explosive when dry
    EUH006: Explosive with or without contact with air
    EUH014: Reacts violently with water
    EUH018: In use may form flammable/explosive vapour-air mixture
    EUH019: May form explosive peroxides
    EUH044: Risk of explosion if heated under confinement

    Health properties
    EUH029: Contact with water liberates toxic gas
    EUH031: Contact with acids liberates toxic gas
    EUH032: Contact with acids liberates very toxic gas
    EUH066: Repeated exposure may cause skin dryness or cracking
    EUH070: Toxic by eye contact
    EUH071: Corrosive to the respiratory tract

    Environmental properties
    EUH059: Hazardous to the ozone layer

     
    Information on certain substances and mixtures
    EUH201: Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
    EUH201A: Warning! Contains lead.
    EUH202: Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
    EUH203: Contains chromium(VI). May produce an allergic reaction.
    EUH204: Contains isocyanates. May produce an allergic reaction.
    EUH205: Contains epoxy constituents. May produce an allergic reaction.
    EUH206: Warning! Do not use together with other products. May release dangerous gases (chlorine).
    EUH207: Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer.
    Comply with the safety instructions.
    EUH208: Contains <name of sensitising substance>. May produce an allergic reaction.
    EUH209: Can become highly flammable in use.
    EUH209A: Can become flammable in use.
    EUH210: Safety data sheet available on request.
    EUH401: To avoid risks to human health and the environment, comply with the instructions for use.
     
  • Sorce : United Nations , 2015
     

 

Safety Information Risk and Safety Phrases
  • Risk Phrases (R)

    R1: Explosive when dry 
    R2: Risk of explosion by shock, friction, fire or other sources of ignition 
    R3: Extreme risk of explosion by shock, friction, fire or other sources of ignition 
    R4: Forms very sensitive explosive metallic compounds 
    R5: Heating may cause an explosion 
    R6: Explosive with or without contact with air
    R7: May cause fire 
    R8: Contact with combustible material may cause fire 
    R9: Explosive when mixed with combustible material 
    R10: Flammable 
    R11: Highly flammable 
    R12: Extremely flammable 
    R14: Reacts violently with water 
    R15: Contact with water liberates extremely flammable gases 
    R16: Explosive when mixed with oxidizing substances 
    R17: Spontaneously flammable in air
    R18: In use, may form flammable/explosive vapor-air mixture 
    R19: May form explosive peroxides 
    R20: Harmful by inhalation 
    R21: Harmful in contact with skin 
    R22: Harmful if swallowed 
    R23: Toxic by inhalation 
    R24: Toxic in contact with skin 
    R25: Toxic if swallowed
    R26: Very toxic by inhalation 
    R27: Very toxic in contact with skin
    R28: Very toxic if swallowed 
    R29: Contact with water liberates toxic gas. 
    R30: Can become highly flammable in use 
    R31: Contact with acids liberates toxic gas 
    R32: Contact with acids liberates very toxic gas R33: Danger of cumulative effects 
    R34: Causes burns 
    R35: Causes severe burns 
    R36: Irritating to eyes 
    R37: Irritating to respiratory system 
    R38: Irritating to skin 
    R39: Danger of very serious irreversible effects 
    R40: Limited evidence of a carcinogenic effect
    R41: Risk of serious damage to eyes
    R42: May cause sensitization by inhalation 
    R43: May cause sensitization by skin contact 
    R44: Risk of explosion if heated under confinement 
    R45: May cause cancer 
    R46: May cause heritable genetic damage 
    R48: Danger of serious damage to health by prolonged exposure 
    R49: May cause cancer by inhalation
    R50: Very toxic to aquatic organisms 
    R51: Toxic to aquatic organisms 
    R52: Harmful to aquatic organisms 
    R53: May cause long-term adverse effects in the aquatic environment 
    R54: Toxic to flora
    R55: Toxic to fauna 
    R56: Toxic to soil organisms 
    R57: Toxic to bees 
    R58: May cause long-term adverse effects in the environment 
    R59: Dangerous for the ozone layer 
    R60: May impair fertility 
    R61: May cause harm to the unborn child 
    R62: Possible risk of impaired fertility 
    R63: Possible risk of harm to the unborn child 
    R64: May cause harm to breast-fed babies
    R65: Harmful: may cause lung damage if swallowed
    R66: Repeated exposure may cause skin dryness or cracking
    R67: Vapours may cause drowsiness and dizziness
    R68: Possible risk of irreversible effects
  • Combination Risk Phrases (R)

    R14/15: Reacts violently with water, liberating extremely flammable gases 
    R15/29: Contact with water liberates toxic, extremely flammable gases 
    R20/21: Harmful by inhalation and in contact with skin 
    R20/22: Harmful by inhalation and if swallowed 
    R20/21/22: Harmful by inhalation, in contact with skin and if swallowed 
    R21/22: Harmful in contact with skin and if swallowed 
    R23/24: Toxic by inhalation and in contact with skin 
    R23/25: Toxic by inhalation and if swallowed 
    R23/24/25: Toxic by inhalation, in contact with skin and if swallowed 
    R24/25: Toxic in contact with skin and if swallowed 
    R26/27: Very toxic by inhalation and in contact with skin 
    R26/28: Very toxic by inhalation and if swallowed 
    R26/27/28: Very toxic by inhalation, in contact with skin and if swallowed 
    R27/28: Very toxic in contact with skin and if swallowed 
    R36/37: Irritating to eyes and respiratory system 
    R36/38: Irritating to eyes and skin 
    R36/37/38: Irritating to eyes, respiratory system and skin 
    R37/38: Irritating to respiratory system and skin 
    R39/23: Toxic: danger of very serious irreversible effects through inhalation 
    R39/24: Toxic: danger of very serious irreversible effects in contact with skin 
    R39/25: Toxic: danger of very serious irreversible effects if swallowed 
    R39/23/24: Toxic: danger of very serious irreversible effects through inhalation and in contact with skin 
    R39/23/25: Toxic: danger of very serious irreversible effects through inhalation and if swallowed 
    R39/24/25: Toxic: danger of very serious irreversible effects in contact with skin and if swallowed 
    R39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 
    R39/26: Very Toxic: danger of very serious irreversible effects through inhalation 
    R39/27: Very Toxic: danger of very serious irreversible effects in contact with skin 
    R39/28: Very Toxic: danger of very serious irreversible effects if swallowed 
    R39/26/27: Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin 
    R39/26/28: Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed 
    R39/27/28: Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed 
    R39/26/27/28: Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 
    R42/43: May cause sensitization by inhalation and skin contact 
    R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation 
    R48/21: Harmful: danger of serious damage to health by prolonged exposure in contact with skin 
    R48/22: Harmful: danger of serious damage to health by prolonged exposure if swallowed 
    R48/20/21: Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin 
    R48/20/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed 
    R48/21/22: Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed 
    R48/20/21/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed 
    R48/23: Toxic: danger of serious damage to health by prolonged exposure through inhalation 
    R48/24: Toxic: danger of serious damage to health by prolonged exposure in contact with skin 
    R48/25: Toxic: danger of serious damage to health by prolonged exposure if swallowed 
    R48/23/24: Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin 
    R48/23/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed 
    R48/24/25: Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed 
    R48/23/24/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed 
    R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 
    R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 
    R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment 
    R68/20: Harmful: possible risk of irreversible effects through inhalation 
    R68/21: Harmful: possible risk of irreversible effects in contact with skin
    R68/22: Harmful: possible risk of irreversible effects if swallowed 
    R68/20/21: Harmful: possible risk of irreversible effects through inhalation and in contact with skin 
    R68/20/22: Harmful: possible risk of irreversible effects through inhalation and if swallowed 
    R68/21/22: Harmful: possible risk of irreversible effects in contact with skin and if swallowed 
    R68/20/21/22: Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed 
  • Safety Phrases (S)

    S1: Keep locked up 
    S2: Keep out of the reach of children 
    S3: Keep in a cool place 
    S4: Keep away from living quarters under… (appropriate liquid to be specified by the manufacturer)
    S5: Keep contents under ... (appropriate liquid to be specified by the manufacturer)
    S6: Keep under ... (inert gas to be specified by the manufacturer) 
    S7: Keep container tightly closed 
    S8: Keep container dry 
    S9: Keep container in a well-ventilated place 
    S12: Do not keep the container sealed 
    S13: Keep away from food, drink and animal feeding stuffs 
    S14: Keep away from ... (incompatible materials to be indicated by the manufacturer)
    S15: Keep away from heat 
    S16: Keep away from sources of ignition - No smoking 
    S17: Keep away from combustible material
    S18: Handle and open container with care 
    S20: When using do not eat or drink
    S21: When using do not smoke
    S22: Do not breathe dust 
    S23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) 
    S24: Avoid contact with skin 
    S25: Avoid contact with eyes 
    S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
    S27: Take off immediately all contaminated clothing 
    S28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 
    S29: Do not empty into drains 
    S30: Never add water to this product 
    S33: Take precautionary measures against static discharges 
    S34: Avoid shock and friction
    S35: This material and its container must be disposed of in a safe way 
    S36: Wear suitable protective clothing 
    S37: Wear suitable gloves 
    S38: In case of insufficient ventilation, wear suitable respiratory equipment
    S39: Wear eye/face protection 
    S40: To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)
    S41: In case of fire and/or explosion do not breathe fumes
    S42: During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer)
    S43: In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add – “Never use water”)
    S45: In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 
    S46: If swallowed, seek medical advice immediately and show this container or label
    S47: Keep at temperature not exceeding ... ºC (to be specified by the manufacturer)
    S48: Keep wet with ... (appropriate material to be specified by the manufacturer)
    S49: Keep only in the original container
    S50: Do not mix with ... (to be specified by the manufacturer) 
    S51: Use only in well-ventilated areas 
    S52: Not recommended for interior use on large surface areas 
    S53: Avoid exposure - obtain special instructions before use 
    S55: Treat using the best available techniques before discharge into drains or the aquatic environment
    S56: Dispose of this material and its container at hazardous or special waste collection point 
    S57: Use appropriate container to avoid environmental contamination 
    S59: Refer to manufacturer/supplier for information on recovery/recycling 
    S60: This material and its container must be disposed of as hazardous waste 
    S61: Avoid release to the environment. Refer to special instructions/safety data sheet
    S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
    S63: In case of accident by inhalation: remove casualty to fresh air and keep at rest 
    S64: If swallowed, rinse mouth with water (only if the person is conscious) 
  • Combination Safety Phrases (S)

    S1/2: Keep locked up and out of the reach of children 
    S3/7: Keep container tightly closed in a cool place 
    S3/7/9: Keep container tightly closed in a cool, well-ventilated place 
    S3/9/14: Keep in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer) 
    S3/9/14/49: Keep only in the original container in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer) 
    S3/9/49: Keep only in the original container in a cool, well-ventilated place 
    S3/14 Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer) 
    S7/8: Keep container tightly closed and dry 
    S7/9: Keep container tightly closed and in a well-ventilated place 
    S7/47: Keep container tightly closed and at temperature not exceeding ... ºC (to be specified by the manufacturer) 
    S20/21: When using do not eat, drink or smoke 
    S24/25: Avoid contact with skin and eyes 
    S27/28: After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of ... (to be specified by the manufacturer) 
    S29/35: Do not empty into drains; dispose of this material and its container in a safe way 
    S29/56: Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point 
    S36/37: Wear suitable protective clothing and gloves 
    S36/37/39: Wear suitable protective clothing, gloves and eye/face protection 
    S36/39: Wear suitable protective clothing and eye/face protection 
    S37/39: Wear suitable gloves and eye/face protection 
    S47/49: Keep only in the original container at temperature not exceeding ... ºC (to be specified by the manufacturer) 

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Hazardous Transportation and Handling Concerns

Hazardous materials are classified by the tariff system. It is important for international shipment of hazardous materials. It is shown in IMDG code (International Maritime Code for Dangerous Goods). The IMDG code has been drawn up by the IMO (International Maritime Organization of the UN). Transportation of dangerous Substances as following according to Recommendation on the Transport of Dangerous Goods, Model Regulations, Twelfth Revised edition, United Nations.

Class Meaning Symblos
     
1 Explosive substances or articles

1.1 Substance and
article which have a
mass explosion hazard


1.2 Substances and
articles which have a
projection hazard
but not a mass
explosion hazard
 

1.3 Substance and
article which have a re
hazard and either a
minor nlast hazard or a
minor projection hazard
or both, but not a mass
explosion hazard

1.4 Substance and
article which present no
signicant hazard
   

1.5 Very insensitive
substances wgich have a
mass explosion hazard
   

1.6 Extremely insensitive
articles which do not
have a mass
explosion hazard
   

2 Gases 2.1) Flammable gases  

2.2) Non-flammable, non-toxic gases  

2.3) Toxic gases    

3 Flamable liquids    

4 Flammable solids; substances liable
to spontaneous combustion; substances which, on contact with water, emit 
ammable gases
4.1) Flamable solid    

4.2) Substances liable to spontaneous combustion    

4.3) Subatances which,in contact with water,emit flammable gases  

5 Oxidizing
substances and
organic peroxides
5.1) Oxidizing substances    

5.2) Organic peroxides  

6 Toxic and
Infectionus
substances
 
6.1) Toxic substanecs    

6.2) Infectious substances    

7 Radioactive material 7A) CategoryI-White, 7B) CategoryII-Yellow, 7C) CategoryIII-Yellow    

7E) Fissile material    

8 Corrosive substances      

9 Miscellaneous dangerous substances and articles,including environmentally hazardous substances        
     

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